Reading the operation of an acid/base-controllable molecular switch by naked eye.
نویسندگان
چکیده
We report a pH-controllable molecular switch whose switching can be monitored by the naked eye; this system involves the formation of a complex between a [2]rotaxane--featuring dibenzylammonium and 4,4'-bipyridinium stations--and a TTF-side-walled molecular clip.
منابع مشابه
طراحی سوئیچ تمام نوری با استفاده از خاصیت غیر خطی Kerr وDIT با نانو کریستال چهار ترازه
We propose a novel two state and all-optical controllable switch using DIT, Kerr effect and interaction between quantum dots (QD) and quantum electrodynamics cavity (CQED). The two state and all-optical controllable switch is coupled to photonic waveguide from a rapid nonlinear environment (photonic crystal) and CQED. We consider the nano-crystal are doped to crystal photonic cavity as a 4-leve...
متن کاملA macrocycle/molecular-clip complex that functions as a quadruply controllable molecular switch.
Herein, we report the synthesis of a molecular clip with TTF side-walls and its binding behavior towards electron-deficient guests, namely the formation of macrocycle/molecular-clip supramolecular complexes in solution. Four different sets of external stimuli--the K(+)/[2.2.2]cryptand, NH(4) (+)/Et(3)N and (p-BrPh)(3)NSbCl(6)/Zn pairs, and heating/cooling cycles-control the movement of this mol...
متن کاملEssential oil composition and total phenolic compounds of naked and normal seed types of different accessions of Cucurbita pepo L. in Iran .
Cucurbita pepo var. styriaca is known as a medicinal crop among other cucurbits and has been cultivated around many decades in some parts of Iran by local farmers. The present study was conducted on 8 accessions of C. pepo seed from various planting zones. All collected seeds were planted in Horticultural Science Research Field of University of Tehran in three replications with two observations...
متن کاملNaphthalene-based Azo-azomethine Chemosensor: Naked Eye Detection of Fluoride in Semi-aqueous Media
A new azo-azomethine chemosensor containing active phenolic sites, H2L, has been designed and synthesized for rapid detection of inorganic fluoride over the other anions, such as Clˉ, Brˉ, Iˉ, AcOˉ, H2PO4ˉ, NO3ˉ, N3ˉ in DMSO/water (90/10) media. The 1H NMR titration revealed that the colorimetric response was considered to be the direct consequence of hydrogen-bond formation between phenolic gr...
متن کاملA chromogenic molecular capsule attributable to dipolar amide resonance structure.
A new chromogenic, self-assembled molecular capsule G@22 is developed by introducing four (N,N-dimethyl-4-aminophenyl) azobenzyl moieties on the upper rim of a resorcin[4]arene-based amidoimino-cavitand. The tuning of conjugation between amido and (N,N-dimethyl-4-aminophenyl)azobenzyl groups by acid-base titration allows naked-eye detection of molecular capsule formation.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 27 شماره
صفحات -
تاریخ انتشار 2006